From garbage to fuel — zeolite catalyst concept

Making fuel from waste is often considered economically unviable due to high temperatures and too much energy being required. However, using a novel catalyst concept, researchers at the Technical University of Munich (TUM) have now managed to significantly reduce the temperature and energy requirements of a key step in the chemical process. The trick being the reaction takes place in very confined spaces inside zeolite crystals.

Ever more electricity is produced decentrally using wind, hydro and solar power plants. “It thus makes sense to decentralise chemical production, as well,” thinks Prof. Johannes Lercher, who heads the Chair of Technical Chemistry II at TU Munich. “Theoretically, any municipality could produce its own fuel or fertiliser.”

To date, this has not been possible because chemical processes require a great deal of energy — more than local renewable energy sources can provide. “We thus aimed at finding new processes to lay the foundations for the distributed production of chemicals, which can be powered using renewable energy sources,” explained the chemist, who is also director of the American Institute for Integrated Catalysis at Pacific Northwest National Laboratory.

His team has now fulfilled one prerequisite for a turnaround in chemical production. In the laboratory, the scientists demonstrated that the temperature required for splitting carbon-oxygen bonds in acidic aqueous solution can be drastically reduced using zeolite crystals. The process also ran much faster than without the zeolite catalysts.

“We thought about how we could apply these biological functions to organic chemistry,” explained Lercher. “While searching for suitable catalysts that accelerate the reaction, we stumbled upon zeolites — crystals with small cavities in which the reactions take place under cramped conditions comparable to those in enzyme pockets.”

Lercher’s team compared the reactions of carbon compounds with acids in a beaker to the same reactions in zeolites. The result: in the crystal cavities, where the reacting molecules, for example alcohols, meet upon the hydronium ions of the acids, reactions run up to 100 times faster and at temperatures just over 100°C.

“Our experiments demonstrate that zeolites as catalysts are similarly effective as enzymes: both significantly reduce the energy levels required by the reactions,” reported Lercher. “The smaller the cavity, the larger the catalytic effect. We achieved the best results with diameters far below one nanometre.”

But why do tight spaces foster the reactivity of molecules? “The force that improves the reaction path is the same as the one that causes wax to stick to a tabletop and that allows geckos to walk on ceilings,” replied Lercher. “The more contact points there are between two surfaces, the larger the adhesion. In our experiments, the organic molecules, which are in an aqueous solution, are literally attracted to the pores in the zeolites.”

Thus, the hydronium ions within the cavities have a significantly greater likelihood of bumping into a reaction partner than those outside. The result is an acid catalysed chemical reaction that takes place faster and with lower energy input.

When they come into contact with hydronium ions, organic molecules such as alcohols lose oxygen. This makes the process suitable to converting bio-oil obtained from organic waste into fuel.

It will take some time, of course, before the new process can be deployed in the field. “We are still working on the fundamentals,” emphasised Lercher. “We hope to use these to create the conditions required for new, decentral chemical production processes that no longer require large-scale facilities.”

Image: Zeolite Catalyst. Source: TUM Fotostelle.

Originally published here.