New carbon capture technology has high capacity and low cost

Tuesday, 04 September, 2012

Carbon capture and storage has been seen as an uneconomical solution to reducing carbon emissions, with the capture of CO2 emissions from a power station currently requiring about 30% of the total electricity it produces. But thanks to Dr Matthew Hill, a researcher at CSIRO Materials Science and Engineering, the capture of carbon emissions is now cheaper than ever before.

Dr Hill has conducted research into metal-organic frameworks (MOFs) - ultraporous crystal-like materials made from very lightweight atoms. Dr Hill’s specially developed MOFs are capable of storing 300% more CO2 than currently used materials - a 160-fold increase in storage density compared to the atmosphere.

The MOFs are able to store so much because of their structure, which is similar to building scaffolding and creates a massive surface area. Hill explained that this surface area includes both outer and inner surface areas, with 99% of it on the inside.

“The maximum surface area created in 7000 m2 for one gram of material, or a spoonful worth of MOFs,” Dr Hill said. “To put this in perspective, a football field is 5000 m2.”

But MOFs have their own challenges as well - for the materials to be financially viable, they need to be re-used. This means the CO2 gas compressed in the framework needs to be released - luckily, 70% of the gas can be released through sunlight alone.

A further problem lies in the large amount of electricity required to transport and store the captured CO2 in underground sites. Hill suggests removing this need for transport and storage by selling the CO2. He and his colleagues are currently working on converting captured CO2 into marketable products such as food for organisms, plastic or low-emission fuel.

Dr Hill originally started working with MOFs in 2008 as a storage option for the hydrogen gas required to fuel a hydrogen car, but later redirected his efforts to the problem of climate change. He has been awarded the 2012 Eureka Prize for Emerging Leader in Science for his research.

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